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Virtually all blood-contacting medical implants and devices initiate immunological events in the form of thrombosis and inflammation. Typically, patients receiving such implants are also given large doses of anticoagulants, which pose a high risk and a high cost to the patient. Thus, the design and development of surfaces with improved hemocompatibility and reduced dependence on anticoagulation treatments is paramount for the success of blood-contacting medical implants and devices. In the past decade, the hemocompatibility of super-repellent surfaces ( i.e. , surfaces that are extremely repellent to liquids) has been extensively investigated because such surfaces greatly reduce the blood–material contact area, which in turn reduces the area available for protein adsorption and blood cell or platelet adhesion, thereby offering the potential for improved hemocompatibility. In this review, we critically examine the progress made in characterizing the hemocompatibility of super-repellent surfaces, identify the unresolved challenges and highlight the opportunities for future research on developing medical implants and devices with super-repellent surfaces.more » « less
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Abstract Due to their unique functionality, superomniphobic surfaces that display extreme repellency toward virtually any liquid, have a wide range of potential applications. However, to date, the mechanical durability of superomniphobic surfaces remains a major obstacle that prevents their practical deployment. In this work, a two‐layer design strategy is developed to fabricate superomniphobic surfaces with improved durability via synergistic effect of interconnected hierarchical porous texture and micro/nanomechanical interlocking. The improved mechanical robustness of these surfaces is assessed through water shear test, ultrasonic washing test, blade scratching test, and Taber abrasion test.more » « less
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Abstract Paper‐based superomniphobic surfaces are of great interest because paper is flexible, inexpensive, lightweight, breathable, and recyclable. Prior reports on paper‐based superomniphobic surfaces have failed to demonstrate high mobility with low surface tension liquids. In order to overcome this issue, in this work, superomniphobic papers are developed through growth of nanofilaments on inherent microfibers of papers without noticeably altering their microscale features (i.e., diameter and distance of the microfibers). These superomniphobic papers display very low roll‐off angle, indicative of ultra‐high droplet mobility, even with low surface tension liquids. Here, a facile method is also developed to control the motion and adhesion of the droplets on the superomniphobic paper. Utilizing such liquid mobility in a controlled manner on these superomniphobic papers, a simple on‐paper pH sensor is fabricated. It is anticipated that this on‐paper, simple, and rapid detection methodology can also be extended to the colorimetric sensing of protein and chemical assays. Further, these superomniphobic papers have potential applications in water–oil separation and enhanced weight‐bearing capacity.more » « less
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